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Q.

What is the correct Nernst equation for reaction taking place in the following cell

Mg(s)Mg2+(aq )Cl((aq) )Cl2(g)(1atm)/Pt

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a

Ecell =Ecell 0.0592n×logCl2Mg2+

b

Ecell =Ecell 0.0592n×logM2+Cl

c

Ecell =Ecell 0.0592n×logMg2+Cl2

d

Ecell =Ecell 0.0592n×logMg2+Cl2

answer is C.

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Detailed Solution

Mg(s)Mg2+(aq)Cl(aq)Cl2(g)(1atm)/Pt

Oxidation half reaction, MgMg2++2e

Reduction half reaction Cl2+2e2ClMg+Cl2Mg2++2Cl

Net cell reaction,

Nernst equation, Ecell =Ecell 0.0591nlogCl2Mg2+

Here n=2

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