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What is the correct order of boiling points of the following alkyl halides ?
I. $C H_{3} - C H_{2} - C H_{2} - C H_{2} - C l$ II. $C H_{3} - C H_{2} - C H_{2} - C H_{2} - B r$
III. IV. ${(H_{3} C)}_{3} C B r$

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II > III > IV>I

I > III > IV >I

II > IV > III > I

I > IV > III > II

answer is A.

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Detailed Solution

$C H_{3} - C H_{2} - C H_{2} - C H_{2} - B r$ > Question Image > ${(H_{3} C)}_{3} C B r$ > $C H_{3} - C H_{2} - C H_{2} - C H_{2} - C l$

More is the branching, lesser will be the surface area and lesser will be the boiling point.

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