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Q.

What is the correct order of boiling points of the following alkyl halides ? 
I. CH3−CH2−CH2−CH2−Cl  II.  CH3−CH2−CH2−CH2−Br
III.  Question Image IV.  (H3C)3CBr

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a

I > III > IV >I  

b

II > IV > III > I

c

I > IV > III > II  

d

II > III > IV>I

answer is A.

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Detailed Solution

CH3−CH2−CH2−CH2−Br>Question Image>(H3C)3CBr>CH3−CH2−CH2−CH2−Cl

More is the branching, lesser will be the surface area and lesser will be the boiling point.

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