Q.

What is the correct order of o/p ratio when e+ attacks the following system?

[Pl PhF          [Q] PhCI

 [RI PhBr      [SI Phl

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a

S < Q < P < R

b

P < Q < R < S

c

P = Q = R = S

d

S < R < Q < P

answer is A.

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Detailed Solution

The +I action of halogens is necessary for the creation of ortho and para products.
The percentage of ortho product generated will increase with the I effect.
The O/P ratio will be higher in this case.
Thus, the O/P ratio is in the following order: A, B, C, and D.

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What is the correct order of o/p ratio when e+ attacks the following system?[Pl PhF          [Q] PhCI [RI PhBr      [SI Phl