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Q.

What is the correct order of spin only magnetic moment (in BM) of Mn+2, Cr+2 and V+2 ?

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a

Mn+2>V+2>Cr+2

b

Mn+2>Cr+2>V+2

c

Cr+2>V+2>Mn+2

d

V+2>Cr+2>Mn+2

answer is C.

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Detailed Solution

  • Spin only magnetic moment depends upon the number of unpaired electrons, more the number of unpaired electrons, greater will be the spin only magnetic moment.

Mn2+=1s22s22p63s23p63d54s0
Number of unpaired electrons =5

Cr2+=1s22s22p63s23p63d44s0
Number of unpaired electrons =4

V2+=1s22s22p63s23p63d34s0
Number of unpaired electrons =3
So, the correct order of spin only magnetic moment is
            Mn2+>Cr2+>V2+

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