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Q.

What is the correct sequence of osmotic pressure of 0.01 M aq. solution of:
(1) Al2(SO4)3 
(2) Na3PO4
(3) BaCl2 
(4) Glucose?

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a

π4>π2>π3>π1

b

π3>π4>π2>π1

c

π3>π4>π1>π2

d

π1>π2>π3>π4

answer is D.

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Detailed Solution

π=iCRT; i=5 for Al2SO43i=4 for Na3PO4i=3 for BaCl2,i=1 for glucose 
So osmotic pressure of :
 Glucose <BaCl2<Na3PO4<Al2SO43

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