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Q.

What is the differentiation between alkanes, alkenes and alkynes?

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Detailed Solution

Alkanes have only single bonds (saturated), alkenes have at least one double bond, and alkynes have at least one triple bond. These three are families of hydrocarbons. Alkanes are saturated (all C–C single bonds), alkenes are unsaturated with C=C double bonds, and alkynes are unsaturated with C≡C triple bonds. Because of bonding, their formulas, reactivity, and uses differ.

PropertyAlkanesAlkenesAlkynes
General formulaCnH2n+2CnH2nCnH2n−2
Bond typeSingle (σ)One or more C=C (σ + π)One or more C≡C (σ + 2π)
SaturationSaturatedUnsaturatedUnsaturated
IsomerismChain isomerismChain, position, geometric (cis/trans)Chain, position
ReactivityLow; substitution (halogenation)Higher; addition reactions (hydrogenation, halogenation)High; addition reactions
ExamplesMethane, ethane, propaneEthene, propene, buteneEthyne (acetylene), propyne
TestingDo not decolorize bromine waterDecolorize bromine water (addition)Decolorize bromine; react with ammoniacal AgNO3 if terminal
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