Q.

What is the equivalent weight of HNO3 in the given reaction ?

4Zn + 10HNO3   4ZnNO32 + NH4NO3 + 3H2O

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a

6310

b

639

c

638 ×  9

d

634 ×  14

answer is C.

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Detailed Solution

(3)

HNO3NH4+

N5+ + 8e-   N3-

n-factor as reductant=8

9 moles of HNO3 is acting as acid, basicity is 1. 

As an acid, equivalent weight = M

Total equivalent weight = M (as acid) +M8( as Reducing agent)=9M8=9×638  

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