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Q.

What is the expected order of reactivity of the following compounds in electrophilic chlorination Cl2+FeCl3

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a

IV > III > II > I

b

I > II > III > IV

c

III > I > IV > II

d

II > III > I > IV

answer is D.

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Detailed Solution

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Reaction with Cl2/FeCl3 is electrophilic  aromatic substitution reaction( EAS )

Reactivity in EAS is increases by electron releasing group and vice versa. 

Compound (II) i smost reactive followed by  (III) . Compound  (IV) is strongly deactivated by - CCl3 followed by compound (I).

 

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