Q.

What is the formal charge on the nitrogen atom in HNO3 ?

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a

+5

b

+3

c

0

d

+1

answer is B.

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Detailed Solution

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The appropriate Lewis structure is HON+(=O)O

The nitrogen atom is quaternized and has a formal positive charge, whereas one of the oxygen atoms has a formal negative charge. Of course, the Lewis structure represents the molecule's neutrality.
Keep in mind that nitric acid dissociates when:

HNO3 (aq) +H2O(l)H3O++NO3

There are 3 formal charges on the nitrate ion 

 ON+(=O)O

Although the anion is again formal charge separated in our depiction, the total charge on the ion is still 1.

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