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Q.
What is the formula of ammonia? What is the chemical formula for ammonia?
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Detailed Solution
Basic Chemical Formulas
Formula Type | Formula | Name/Description | Explanation |
Molecular Formula | NH₃ | Ammonia | Shows the exact number of atoms: 1 nitrogen atom bonded to 3 hydrogen atoms |
Empirical Formula | NH₃ | Ammonia | Simplest whole number ratio of atoms (same as molecular in this case) |
Structural Formula | H-N-H with lone pair | Ammonia structure | Shows how atoms are connected; nitrogen has one lone pair of electrons |
Condensed Formula | NH₃ | Ammonia | Simplified representation showing atom types and quantities |
Ammonia in Aqueous Solutions
Formula Type | Formula | Name/Description | Explanation |
Ammonia in Water | NH₃ + H₂O ⇌ NH₄⁺ + OH⁻ | Base dissociation | Ammonia acts as a weak base, accepting protons from water |
Ammonium Hydroxide | NH₄OH | Ammonium hydroxide | Traditional representation of ammonia solution (though NH₃·H₂O is more accurate) |
Ammonium Ion | NH₄⁺ | Ammonium cation | Formed when ammonia accepts a proton (H⁺) |
Hydroxide Ion | OH⁻ | Hydroxide anion | Released when ammonia acts as a base |
Equilibrium Constants and pH Calculations
Formula Type | Formula | Name/Description | Explanation |
Kb Expression | Kb = [NH₄⁺][OH⁻]/[NH₃] | Base dissociation constant | Measures strength of ammonia as a base; Kb = 1.8 × 10⁻⁵ at 25°C |
Ka Expression | Ka = [NH₃][H₃O⁺]/[NH₄⁺] | Acid dissociation constant | For ammonium ion acting as acid; Ka = 5.6 × 10⁻¹⁰ at 25°C |
pKb Formula | pKb = -log(Kb) | Negative logarithm of Kb | pKb = 4.74 for ammonia at 25°C |
pKa Formula | pKa = -log(Ka) | Negative logarithm of Ka | pKa = 9.25 for ammonium ion at 25°C |
Kw Relationship | Ka × Kb = Kw = 1.0 × 10⁻¹⁴ | Ion product of water | Relationship between Ka and Kb for conjugate acid-base pairs |
pH and pOH Calculations
Formula Type | Formula | Name/Description | Explanation |
pH of NH₃ Solution | pH = 14 - pOH | pH calculation | After finding pOH from Kb expression |
pOH from Kb | pOH = ½(pKb - log C) | Weak base approximation | C is the initial concentration of NH₃ |
Henderson-Hasalbalch | pH = pKa + log([NH₃]/[NH₄⁺]) | Buffer equation | For NH₃/NH₄⁺ buffer systems |
Ion Concentration | [OH⁻] = √(Kb × C) | Hydroxide concentration | Approximation for weak base solutions |
Industrial and Synthesis Formulas
Formula Type | Formula | Name/Description | Explanation |
Haber Process | N₂ + 3H₂ ⇌ 2NH₃ | Industrial synthesis | High temperature and pressure synthesis of ammonia |
Catalyzed Haber | N₂ + 3H₂ → 2NH₃ (with Fe catalyst) | Catalyzed synthesis | Iron catalyst increases reaction rate |
Enthalpy Change | ΔH = -92.4 kJ/mol | Heat of formation | Energy released when forming NH₃ from elements |
Combustion and Decomposition
Formula Type | Formula | Name/Description | Explanation |
Complete Combustion | 4NH₃ + 3O₂ → 2N₂ + 6H₂O | Burning in limited oxygen | Produces nitrogen gas and water |
Catalytic Oxidation | 4NH₃ + 5O₂ → 4NO + 6H₂O | Ostwald process | First step in nitric acid production |
Thermal Decomposition | 2NH₃ → N₂ + 3H₂ | High temperature breakdown | Reverse of Haber process |
Physical Property Formulas
Formula Type | Formula | Name/Description | Explanation |
Molar Mass | M = 17.03 g/mol | Molecular weight | Sum of atomic masses: N(14.01) + 3H(1.008) |
Density (gas, STP) | ρ = 0.771 g/L | Gas density | At standard temperature and pressure |
Density (liquid) | ρ = 0.682 g/cm³ | Liquid density | At -33.34°C (boiling point) |
Ideal Gas Law | PV = nRT | Gas behavior | Where n = moles of NH₃ |
Concentration and Molarity
Formula Type | Formula | Name/Description | Explanation |
Molarity | M = moles NH₃ / L solution | Molar concentration | Standard concentration unit |
Mass Percentage | % = (mass NH₃ / total mass) × 100 | Weight percentage | Common for aqueous solutions |
ppm Conversion | ppm = (mg NH₃ / L solution) | Parts per million | For dilute environmental samples |
Normality | N = M × 1 | Normal concentration | For NH₃, normality equals molarity (monoprotic base) |
Constants and Values
Parameter | Value | Units | Conditions |
Kb (Base constant) | 1.8 × 10⁻⁵ | - | 25°C |
pKb | 4.74 | - | 25°C |
Boiling Point | -33.34 | °C | 1 atm |
Melting Point | -77.73 | °C | 1 atm |
Critical Temperature | 132.25 | °C | - |
Bond Angle (H-N-H) | 106.67 | degrees | Gas phase |
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