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Q.

What is the formula of nitric acid?

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Detailed Solution

Basic Chemical Formulas

Formula TypeFormulaExplanation
Chemical FormulaHNO₃Basic chemical formula showing one hydrogen, one nitrogen, and three oxygen atoms
Molecular FormulaHNO₃Same as chemical formula - represents the actual number of atoms in one molecule
Empirical FormulaHNO₃Simplest whole number ratio of atoms (same as molecular formula for nitric acid)
Condensed FormulaHONO₂Alternative representation showing the structural arrangement

Structural Representations

TypeFormula/StructureDescription
Structural FormulaH-O-NO₂Shows how atoms are bonded together
Lewis StructureH-O-N(=O)-OComplete electron dot structure with bonds
IUPAC NameNitric acidOfficial chemical name
Common NamesAqua fortis, Spirit of niterHistorical and common names

Concentration-Based Formulas

Concentration TypeFormula/CompositionDetails
Concentrated Nitric Acid68-70% HNO₃Commercial concentrated form
Dilute Nitric Acid<20% HNO₃ in H₂OCommonly used in laboratories
Fuming Nitric Acid>90% HNO₃ + NO₂Red/yellow fuming, highly concentrated
Molar ConcentrationM = n/VWhere M = molarity, n = moles, V = volume in liters

Production Formulas (Ostwald Process)

StepChemical EquationProcess Description
Step 14NH₃ + 5O₂ → 4NO + 6H₂OAmmonia oxidation (catalyst: Pt)
Step 22NO + O₂ → 2NO₂Nitrogen monoxide oxidation
Step 33NO₂ + H₂O → 2HNO₃ + NONitrogen dioxide absorption in water
OverallNH₃ + 2O₂ → HNO₃ + H₂ONet reaction for nitric acid production

Dissociation and Ionization

ProcessChemical EquationExplanation
Complete DissociationHNO₃ → H⁺ + NO₃⁻Strong acid - complete ionization
In WaterHNO₃ + H₂O → H₃O⁺ + NO₃⁻Proton transfer to water
Ka ExpressionKa = [H⁺][NO₃⁻]/[HNO₃]Very large value (strong acid)

Important Reactions with Metals

Reaction TypeGeneral FormulaExample
With Active MetalsM + HNO₃ → M(NO₃)ₙ + NOₓ + H₂OZn + 4HNO₃ → Zn(NO₃)₂ + 2NO₂ + 2H₂O
With CopperCu + 4HNO₃ → Cu(NO₃)₂ + 2NO₂ + 2H₂OBrown gas (NO₂) evolution
With SilverAg + 2HNO₃ → AgNO₃ + NO₂ + H₂ODilute acid produces NO instead

Reactions with Non-Metals

ReactantChemical EquationProducts
CarbonC + 4HNO₃ → CO₂ + 4NO₂ + 2H₂OCarbon dioxide and nitrogen dioxide
SulfurS + 6HNO₃ → H₂SO₄ + 6NO₂ + 2H₂OSulfuric acid formation
PhosphorusP + 5HNO₃ → H₃PO₄ + 5NO₂ + H₂OPhosphoric acid production

Physical Property Formulas

PropertyFormula/ValueUnits
Molecular Weight63.01 g/molGrams per mole
Density (pure)1.51 g/cm³At 25°C
Boiling Point83°C (181°F)At 1 atm pressure
Melting Point-42°C (-44°F)Freezing point

Titration and Analytical Formulas

CalculationFormulaApplication
MolarityM = (n × 1000)/Vn = moles, V = volume in mL
NormalityN = M × nn = number of H⁺ ions (1 for HNO₃)
pH CalculationpH = -log[H⁺]For dilute solutions
NeutralizationM₁V₁ = M₂V₂Acid-base titrations

Environmental and Safety Formulas

ProcessChemical EquationEnvironmental Impact
Acid Rain Formation4NO₂ + 2H₂O + O₂ → 4HNO₃Major contributor to acid precipitation
Ozone DepletionHNO₃ + hν → OH + NO₂Photochemical decomposition
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