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Q.
What is the formula of nitric acid?
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Detailed Solution
Basic Chemical Formulas
| Formula Type | Formula | Explanation |
| Chemical Formula | HNO₃ | Basic chemical formula showing one hydrogen, one nitrogen, and three oxygen atoms |
| Molecular Formula | HNO₃ | Same as chemical formula - represents the actual number of atoms in one molecule |
| Empirical Formula | HNO₃ | Simplest whole number ratio of atoms (same as molecular formula for nitric acid) |
| Condensed Formula | HONO₂ | Alternative representation showing the structural arrangement |
Structural Representations
| Type | Formula/Structure | Description |
| Structural Formula | H-O-NO₂ | Shows how atoms are bonded together |
| Lewis Structure | H-O-N(=O)-O | Complete electron dot structure with bonds |
| IUPAC Name | Nitric acid | Official chemical name |
| Common Names | Aqua fortis, Spirit of niter | Historical and common names |
Concentration-Based Formulas
| Concentration Type | Formula/Composition | Details |
| Concentrated Nitric Acid | 68-70% HNO₃ | Commercial concentrated form |
| Dilute Nitric Acid | <20% HNO₃ in H₂O | Commonly used in laboratories |
| Fuming Nitric Acid | >90% HNO₃ + NO₂ | Red/yellow fuming, highly concentrated |
| Molar Concentration | M = n/V | Where M = molarity, n = moles, V = volume in liters |
Production Formulas (Ostwald Process)
| Step | Chemical Equation | Process Description |
| Step 1 | 4NH₃ + 5O₂ → 4NO + 6H₂O | Ammonia oxidation (catalyst: Pt) |
| Step 2 | 2NO + O₂ → 2NO₂ | Nitrogen monoxide oxidation |
| Step 3 | 3NO₂ + H₂O → 2HNO₃ + NO | Nitrogen dioxide absorption in water |
| Overall | NH₃ + 2O₂ → HNO₃ + H₂O | Net reaction for nitric acid production |
Dissociation and Ionization
| Process | Chemical Equation | Explanation |
| Complete Dissociation | HNO₃ → H⁺ + NO₃⁻ | Strong acid - complete ionization |
| In Water | HNO₃ + H₂O → H₃O⁺ + NO₃⁻ | Proton transfer to water |
| Ka Expression | Ka = [H⁺][NO₃⁻]/[HNO₃] | Very large value (strong acid) |
Important Reactions with Metals
| Reaction Type | General Formula | Example |
| With Active Metals | M + HNO₃ → M(NO₃)ₙ + NOₓ + H₂O | Zn + 4HNO₃ → Zn(NO₃)₂ + 2NO₂ + 2H₂O |
| With Copper | Cu + 4HNO₃ → Cu(NO₃)₂ + 2NO₂ + 2H₂O | Brown gas (NO₂) evolution |
| With Silver | Ag + 2HNO₃ → AgNO₃ + NO₂ + H₂O | Dilute acid produces NO instead |
Reactions with Non-Metals
| Reactant | Chemical Equation | Products |
| Carbon | C + 4HNO₃ → CO₂ + 4NO₂ + 2H₂O | Carbon dioxide and nitrogen dioxide |
| Sulfur | S + 6HNO₃ → H₂SO₄ + 6NO₂ + 2H₂O | Sulfuric acid formation |
| Phosphorus | P + 5HNO₃ → H₃PO₄ + 5NO₂ + H₂O | Phosphoric acid production |
Physical Property Formulas
| Property | Formula/Value | Units |
| Molecular Weight | 63.01 g/mol | Grams per mole |
| Density (pure) | 1.51 g/cm³ | At 25°C |
| Boiling Point | 83°C (181°F) | At 1 atm pressure |
| Melting Point | -42°C (-44°F) | Freezing point |
Titration and Analytical Formulas
| Calculation | Formula | Application |
| Molarity | M = (n × 1000)/V | n = moles, V = volume in mL |
| Normality | N = M × n | n = number of H⁺ ions (1 for HNO₃) |
| pH Calculation | pH = -log[H⁺] | For dilute solutions |
| Neutralization | M₁V₁ = M₂V₂ | Acid-base titrations |
Environmental and Safety Formulas
| Process | Chemical Equation | Environmental Impact |
| Acid Rain Formation | 4NO₂ + 2H₂O + O₂ → 4HNO₃ | Major contributor to acid precipitation |
| Ozone Depletion | HNO₃ + hν → OH + NO₂ | Photochemical decomposition |
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