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Q.

What is the general formula for esters?

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Detailed Solution

An ester is an organic compound derived from a carboxylic acid and an alcohol. Esters are characterized by the presence of the ester functional group (-COO-) and are commonly found in fats, oils, and many naturally occurring compounds.

General Ester Formula

Basic Structural Formula

R-COO-R'

Where:

  • R = alkyl or aryl group from the carboxylic acid
  • COO = ester functional group
  • R' = alkyl or aryl group from the alcohol

Condensed Formula

R-CO₂-R' or RCOOR'

Functional Group Formula

The ester functional group is represented as: -COO- or -CO₂-

Ester Formulas by Type

Ester TypeGeneral FormulaStructural RepresentationExample
Simple Aliphatic EsterR-COO-R'![Simple ester structure]CH₃COOCH₃
Aromatic EsterAr-COO-R or R-COO-Ar![Aromatic ester structure]C₆H₅COOCH₃
DiesterR-COO-R'-OOC-R![Diester structure]CH₃COO-CH₂-CH₂-OOCCH₃
Cyclic Ester (Lactone)Cyclic R-COO-![Lactone structure]γ-butyrolactone

Common Ester Examples

Class 10 Level Esters

Ester NameMolecular FormulaStructural FormulaSource/Use
Methyl AcetateC₃H₆O₂CH₃COOCH₃Solvent, paint thinner
Ethyl AcetateC₄H₈O₂CH₃COOCH₂CH₃Nail polish remover
Methyl SalicylateC₈H₈O₃HOC₆H₄COOCH₃Oil of wintergreen
Ethyl ButyrateC₆H₁₂O₂CH₃CH₂CH₂COOCH₂CH₃Pineapple flavoring

Advanced Level Esters

Ester NameMolecular FormulaStructural FormulaApplications
AspirinC₉H₈O₄CH₃COOC₆H₄COOHMedicine
TriglyceridesVariable(RCOO)₃-glycerolFats and oils
Polyethylene Terephthalate(C₁₀H₈O₄)ₙ[-OOC-C₆H₄-COO-CH₂CH₂-]ₙPlastic bottles

Ester Formation Reactions

1. Esterification (Fischer Esterification)

Formula:

R-COOH + R'-OH ⇌ R-COO-R' + H₂O

Example:

CH₃COOH + C₂H₅OH ⇌ CH₃COOC₂H₅ + H₂O
(Acetic acid) + (Ethanol) ⇌ (Ethyl acetate) + (Water)

2. Acid Chloride Method

Formula:

R-COCl + R'-OH → R-COO-R' + HCl

3. Anhydride Method

Formula:

(R-CO)₂O + R'-OH → R-COO-R' + R-COOH

Nomenclature and Naming

IUPAC Naming System

Format: [Alkyl group from alcohol] + [Alkanoate from acid]

EsterIUPAC NameCommon Name
CH₃COOCH₃Methyl ethanoateMethyl acetate
CH₃COOC₂H₅Ethyl ethanoateEthyl acetate
C₂H₅COOCH₃Methyl propanoateMethyl propionate
HCOOC₂H₅Ethyl methanoateEthyl formate
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