Q.

What is the number of unpaired electron(s) in the highest occupied molecular orbital of the following
species N2;N2+;O2;O2+?

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a

2, 1, 0, 1

b

0, 1, 0, 1

c

0, 1, 2, 1

d

2, 1, 2, 1

answer is D.

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Detailed Solution

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N2:σ1s2<σ1s2<σ2s2<σ2s2<π2px2=π2py2<σ2pz20

N2+:σ1s2<σ1s2<σ2s2<σ2s2<π2px2=π2py2<σ2pz11O2:σ1s2<σ1s2<σ2s2<σ2s2<σ2pz2<π2px2=π2py2<π2px1=π2py12O2+:σ1s2<σ1s2<σ2s2<σ2s2<σ2pz2<π2px2=π2py2<π2px1=π2py1

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