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Q.

What is the pressure of 2 moles of NH3 at 270C when its volume is 5 litre in van der Waals equation (a = 4.17, b = 0.03711) ?

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a

10.33 atm

b

9.33 atm

c

9.74 atm

d

9.2 atm

answer is B.

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Detailed Solution

P+n2aV2 V-nb = nRT P + 22 x 4.1752 5-2 x .03711= 2 x .0821 x 300 P = 2 x .0821 x 3005-2 x .03711 - 4.7 x 2252  10-0.66 = 9.3 atm

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