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Q.

What is the ratio of [Mg2+]  and  [Al3+] in 1 litre saturated solution of  Mg(OH)2 and Al(OH)3  by making proper approximation ?  Given  Kspof Mg(OH)2=4×1012Ksp of Al(OH)3=1×1033
 Report your answer in multiples of  1017. (Round off to nearest integer)
 

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answer is 8.

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Detailed Solution

 Mg(OH)2  Mg2++2O¯H
                              x        2x + 3y
 Al(OH)3  Al3++3O¯H
                                      y       2x + 3y
 As Kspof Mg(OH)2>>Kspof Al(OH)3
 2x+3y2x
Now
 [Mg2+][O¯H]2=4×1012 x×(2x)2=4×1012 x=104 [Al3+][O¯H]3=1×1033 y×(2x)3=1×1033 y×8×1012=1×1033 y=10218.            xy=10410218=8×1017
 

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