What kind of isomerism is shown by the pairs of following complex compounds?(a) [Pt(H2O)4CI2]CI22H2O and [Pt(H2O)5CI]CI3.H2O,(b) [Cu(NH3)4][Ni(CN)4] and [Ni(NH3)4][Cu(CN)4].

(a) [Pt(H2O)4CI2]CI22H2O and [Pt(H2O)5CI]CI3.H2O. Exhibit Hydrated isomerism(b) [Cu(NH3)4][Ni(CN)4] and [Ni(NH3)4][Cu(CN)4]. Exhibit Coordination isomerism

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What kind of isomerism is shown by the pairs of following complex compounds?
(a) [Pt(H₂O)₄CI₂]CI₂2H₂O and [Pt(H₂O)₅CI]CI₃.H₂O,
(b) [Cu(NH₃)₄][Ni(CN)₄] and [Ni(NH₃)₄][Cu(CN)₄].

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Detailed Solution

(a) [Pt(H₂O)₄CI₂]CI₂2H₂O and [Pt(H₂O)₅CI]CI₃.H₂O. Exhibit Hydrated isomerism
(b) [Cu(NH₃)₄][Ni(CN)₄] and [Ni(NH₃)₄][Cu(CN)₄]. Exhibit Coordination isomerism