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Q.

What product is formed by mixing the solution of  K4Fe(CN)6 with the solution of FeCl3 in complete absence of air?

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a

Ferro ferricyanide 

b

Ferric ferrocyanide 

c

Ferric ferricyanide

d

None of these

answer is D.

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Detailed Solution

FeCl3+K4Fe(CN)6K2FeFe(CN)6(White ppt.)

If we add ferric chloride over potassium ferrocyanide, it forms a white precipitate that will become blue. because being small quantity of ferric chloride, not all potassium is displaced.

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