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Q.

What volume of 0.2 M Ba(MnO4)2 solution is required for complete oxidation of 25 gm of 89.6% pure Fe C2O4 in acidic medium according to the reaction MnO4+FeCr2O4Fe+3+Cr2O72+Mn+2

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a

700 ml

b

175 ml

c

350 ml

d

200 ml

answer is C.

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Detailed Solution

No of milli equivalents of Ba(MnO4 )2 =No.
of milli equivalents of FeCr2 O4
n - factor of Ba(MnO4 )2 = 10
n - factor of FeCr2 O4 = 7
V×0.2×10=25×89.6×103100×2247 V=350ml

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