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Q.

What weights of P4O6 and P4O10 will be produced by the combustion of  of 31g of P4 in 32g of oxygen leaving no P4 and O2 ?

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a

2.75g, 219.5g

b

27.5g, 35.5g

c

55g, 71g

d

17.5g,190.5g

answer is B.

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Detailed Solution

 Percentage of P4O6=(31×4)×100(31×4+32×6)=56.3437%P

 Percentage of P4O10=43.6420P

31gP=31/(31+32)=49.2063%P

So,

100%P4O6=56.3437%2%P4O6=49.2063%0%P4O6=43.6420%

Find the value of z

z100=(49.206343.6420)(56.343743.6420)z=43.808%P4O6

By the law of the Conservation of Matter, the total mass of P4O6 and P4O10=31g+32g=63g

43.808% of 63g=27.6gP4O6

63g27.6g=35.4gP4O10

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