Q.

What will be the molar solubility S of a solid salt with general formula Mxp+Xyq- ?

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a

Kspxx·yyx+y

b

Kspxy·yx1/x+y

c

Kspxx·yy1/x+y

d

Kspxy·yxx+y

answer is C.

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Detailed Solution

A solid salt,of the general formula, Mxp+Xyq- with molar solubility ,S in equilibrium with its saturated solution may be represented by the equation,
MxXy(s)xMp+(aq)+yXq-'(aq)

 (where x×p+=y×q-

                                       (where x×p+=y×q-

And its solubility product constant is given by
Ksp=Mp+xXq-y=(xS)x(yS)y

KSP= xx·yy·S(x+y)

S(x+y)=KspXx,Yy or  S = Ksp/Xx·Yy1/x+y

 

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