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Q.

What will be the molecular weight of NaCl determined experimentally from elevation in the boiling point or depression in freezing point method?

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a

>58.5

b

<58.5

c

=58.5

d

None of these

answer is A.

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Detailed Solution

NaClNa++Cl

NaCl furnishes two ions on complete dissociation.
so i=2 and
Normal molecular weight of electrolyte >Experimental molecular weight.

i=MTheo MObs [Put i=2]

MObe <MTheo  =58.5

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