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Q.

What will be the pH at the equivalence point during the titration of a 100 mL 0.2 M solution of CH3COONa with 0.2 M solution of HCl ?

Ka=2×105

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a

3+log2

b

3log2

c

3log2

d

3+log2

answer is A.

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Detailed Solution

The chemical formula for the sodium titration reaction is balanced.

HCl and acetate are  CH3COONa+HClCH3COOH+NaCl

To create 200 ml of 0.1 M sodium acetate, 100 ml of 0.2 M sodium acetate must be combined with 100 ml of 0.2 M HCl.

pH=12pKalogCH3COOH

pH=12[4.69log0.1]=2.849=3log2

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