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Q.

What will be the volume strength of 100 mL of H2O2 required to react completely with 61 mL of KMnO4 in acidic medium? (Given that 61 mL of KMnO4 reacts completely with 5 mL of 1 M K4Fe(CN)6, where it converts into K+,Fe3+,CO32 and NO3 )

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a

19.8 V

b

34.62 V

c

18.8 V

d

17.31 V 

answer is A.

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Detailed Solution

Here, the value of Molarity,

61×M×5=5×1×61M=1

Now,

100×M×2=61×1×5M=1.525

So, Volume strength,

 V.S. =11.35×1.525 V.S.=17.31

Thus, the correct option is A.

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