Q.

What would be the amount of heat released when an aqueous solution containing 0.5 mole of HNO3

is mixed with 0.3 mole of  OH (enthalpy of neutralization is – 57.1 kJ) ?

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a

4.1 kcal

b

17.1 kJ  

c

4100 cal 

d

28.5 kJ

answer is B, C, D.

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Detailed Solution

HNO3 + OH H2O + NO3

The enthalpy of neutralization is −57.1 kJ/mol.
0.3 mole of HNO3​ will react with 0.3 moles of OH. The heat released is:

0.3 mol×-57.1 kJ/mol=17.1 kJ or 4.1 kcal or 4100 cal

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What would be the amount of heat released when an aqueous solution containing 0.5 mole of HNO3is mixed with 0.3 mole of  OH− (enthalpy of neutralization is – 57.1 kJ) ?