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Q.

What would happen when a solution of potassium chromate is treated with an excess of dilute nitric acid?

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a

CrO42- is oxidised to +7 state of Cr

b

CrO42 is reduced to +3 state of Cr

c

Cr2O72 and H2O are formed 

d

Cr3+ and Cr2O72 are formed

answer is C.

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Detailed Solution

2K2CrO4+2HNO3K2Cr2O7+2KNO3+H2OThe oxidation state of chromium in K2Cr2O7  ​is +6, whereas the oxidation state of nitrogen in HNO3 is +5.

Since the maximum oxidation state of nitrogen is +5, so it won’t get oxidize further. Rather it will react to form dichromate ion and a water molecule ( Cr2O72- and  H2O ).

The equation involved is:

2K2CrO4+2HNO3K2Cr2O7+2KNO3+H2O

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