Q.

When 3,3-Dimethyl -2-butanol is heated with H2SO4 , the major product obtained is

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a

2,3-Dimethyl-2-butene

b

3,3-Dimethyl-1-butene

c

cis and trans isomers of (b)

d

2,3-Dimethyl-1-butene

answer is B.

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Detailed Solution

Secondary and tertiary alcohols dehydrated under milder conditions Formation of carbocation is rate determining step of reaction, generally prefers to form more substituted carbocation

The product is formed through rearrangement of the intermediate carbocation.

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