When phenol is treated with bromine in the presence of $C S_{2}$ as solvent at $273 K$ , it gives

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2,4-Diromophenol

2,4,6-Tribromophenol

$o -$ and $p -$ Bromophenol

$m -$ Bromophenol

answer is B.

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Detailed Solution

When reaction of phenol with bromine is carried out in solvents of low polarity such as $C H C l_{3}$ or $C S_{2}$ and at low temp $o -$ Bromo phenol and $p -$ Bromo phenol are formed.

So in this mixture $p -$ Bromo phenol is the major product.

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