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Q.

When 0.78 g of Al(OH)3 is dehydrated to get Al2O3 which is reacted with 6 milliequivalents of HCl. The equivalents of AlCl3 formed are: 

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a

5.0×101

b

3×103

c

2

d

2.5

answer is B.

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Detailed Solution

Al(OH)3DehydrationAl2O36 milliequivalentsAlCl3

Calculate the milliequivalents of Al(OH)3 is:

Milliequivalent of Al(OH)3=WeightMolecular weightvalency×1000 =0.78783×1000 =3

Milliequivalents of Al2O3 is also 3 because milliequivalents of Al(OH)3 and Al2O3 is same. Milliequivalents of Al2O3 and AlCl3 is also same because HCl is present in excess. Therefore, milliequivalents of AlCl3 is also 3. Equivalents of AlCl3 is:

Equivalents of AlCl3=3×11000 =3×10-3

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