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Q.

When 1,1-dichloropropane and 2,2-dichloro propane are reacted separately with aqueous potassium hydroxide solution, compounds A and B are formed. Both A and B gave the same product C on reduction using amalga-matedzinc and HCl. Identify C.

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a

Propane

b

Propyl alcohol

c

 Isopropyl alcohol

d

Propyl chloride

answer is D.

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Detailed Solution

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2, 2-dichloropropane is hydrolyzed to propane-2,2-diol in the presence of KOH, which then loses a water molecule to generate acetone (compound A). Acetone is reduced by Clemmensen to propane in the presence of Zn/Hg and concentrated HCl (compound B). Methylene group is created by reducing a carbonyl group.he product C is given in the above figure. Some in the case of 1,1 – dichloropropane.

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Hence , the correct option is (D).Propane.

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