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Q.

When 1 g of anhydrous oxalic acid is burnt at 25°C, the amount of heat liberated is 2.835 kJ. ΔH combustion is (oxalic acid : C2H2O4)

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a

–445.65 kJ

b

–395.24 kJ      

c

–255.15 kJ

d

–155.16 kJ

answer is A.

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Detailed Solution

Question ImageWe know,

ΔHcombustion = Amount of heat liberated when

1 mole of substance reacts with oxygen.

Mol. wt. of oxalic acid = 90 g mol–1

1 g oxalic acid liberates 2.835 kJ

90 g (1 mole) oxalic acid liberates 2.835 × 90 kJ

mol–1 = 255.15 kJ

Heat involved = – 255.15 Kj

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When 1 g of anhydrous oxalic acid is burnt at 25°C, the amount of heat liberated is 2.835 kJ. ΔH combustion is (oxalic acid : C2H2O4)