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Q.

When 1 mole of carbon is converted into 1 mole of CO2, the heat liberated is same :

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a

irrespective of whether the volume is kept constant or pressure is kept constant

b

irrespective of the temperature at which the reaction is carried out

c

whether the carbon is in the form of diamond or graphite

d

whether the carbon is in gaseous state or solid state. 

answer is A.

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Detailed Solution

The reaction takes place as,

C(s)+O2(g)CO2(g)

ΔH=ΔU+ΔngRT=0

So, the heat liberated is same irrespective of whether the volume is kept constant or pressure is kept constant.

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