Q.

When 10 mL of ethyl alcohol (density = 0.7893 g ml-1) is mixed with 20 mL of water (density 0.9971 g mL-1) at 25oC, the final solution has a density of 0.9571 g mL-1. The percentage change in total volume on mixing is

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a

3.1%

b

2.4%

c

1%

d

None of these

answer is A.

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Detailed Solution

Total weight of alcohol and water

=10×0.7893+20×0.9971

 Volume of mixture =10×0.7893+20×0.99710.9571=29.08 mL Change in volume =(20+10)29.08 =0.92 mL % change in volume =0.92×100303.06%                                                              3.1% 

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