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Q.

When 100 ml of a mixture of O2 and O3 was passed through turpentine, there was a reduction of volume by 20 ml. When 100 ml of such a mixture is heated, the volume increases to (22×n)ml. Find the value of n.

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answer is 5.

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Detailed Solution

Ozone is highly soluble in turpentine. Thus, the decrease in volume of 20 ml is due to the solubility of ozone. Thus 100ml of a mixture contains 20 ml of ozone.

 

On heating, 20 ml of ozone decomposes to form 30 ml of oxygen. The net increase in volume will be (30−20)=10ml.

When 100 ml of such a mixture is heated, the volume increases to (22×5)ml. the value of n=5.

 

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