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Q.

When 2g of a gas A is introduced into an evacuated flask kept at 25ºC, the pressure is found to be 1 atmosphere. If 3g of another gas is then added to the same flask, the total pressure becomes 1.5 atm. Assuming ideal behaviour, the ratio of their molecular weights MA : MB is

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a

3 : 1

b

3 : 2

c

2 : 3

d

1 : 3

answer is B.

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Detailed Solution

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When 2 grams of a gas A is introduced in an evacuated flask kept at 25oC; the pressure was found to be 1 atm .i.e.

Partial Pressure of gas A = 1 atm.

And let moles be nA​=2​/MA

if 3 g of another gas B is then added to the same flask;

Partial Pressure of gas B = 1.5 atm –  1 atm. = 0.5 atm

moles of gas B  =​3/MB

Again the temp and volume are constant therefore,

 P1n1= P2n2  MAMB=13    

 

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