Q.

When 5 mL, of a  1.0 M  HCl  solution is mixed with 5 mL of a 0.1M   NaOH  solution temperature of solution increases by t   0C. which of the following can be predicted from this observation 

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a

If 5 mL of  0.1M   HCl is mixed with 5 mL 0.1 M, NH3 solution, the temperature rise will be less than  t0C

b

If 10 mL of 1.0 M   HCl  is mixed with 10 mL of 0.1  M  NaCl,  the temperature rise will be  2t0C

c

If 10 mL   of  1.0 M   HCl is mixed with 10 mL of 0.1 M  NaOH,   the temperature rise will be  2t0C

d

If 5 mL   of  1.0 M   CH3COOH  is mixed with 5 mL of 0.1M   NaOH,   the  temperature  rise will be less than  t0C

answer is A, B.

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Detailed Solution

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Reaction proceeds by limiting reagent only. Enthalpy of neutralization decreases, when acid or base or both are weak 

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