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Q.

When 5 moles of He gas expand isothermally and reversibly at 300 K from 10 litre to 20 litre, the magnitude of the maximum work obtained is _______ J. [nearest integer] (Given: R=8.3 J K-1 mol-1 and log2=0.3010 )

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answer is 8630.

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Detailed Solution

The magnitude of the maximum work obtained is 8630 J.

To calculate the maximum work obtained when a gas expands isothermally and reversibly, we can use the formula for work done in an isothermal expansion of an ideal gas:

W=nRTln(VfVi)W = -nRT \ln \left( \frac{V_f}{V_i} \right)

Where:

  • W is the work done (in joules),
  • n is the number of moles of gas,
  • R is the gas constant (8.314 J/mol·K),
  • T is the temperature in Kelvin,
  • V2​ is the final volume,
  • V1 is the initial volume.

n=5 mol
T=300 K
V1=10 L
V2=20 L
W=-nRTnV2 V1
=-5×8.3×300×n2010
=-8630.38 J

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When 5 moles of He gas expand isothermally and reversibly at 300 K from 10 litre to 20 litre, the magnitude of the maximum work obtained is _______ J. [nearest integer] (Given: R=8.3 J K-1 mol-1 and log2=0.3010 )