Q.

When 50cm3 of 0.2 N H2SO4 is mixed with 50 cm3 of 1 N KOH, the heat liberated is

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a

57.3 KJ

b

11.45 KJ

c

573 KJ

d

573 J

answer is D.

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Detailed Solution

Number of equivalents of H+ = 0.05 ×0.2 = 0.01

Number of equivalents of OH- = 0.05 ×1 = 0.05

limiting reagent is acid

heat liberated = 0.01×57.3 = 0.573kJ = 573J

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When 50cm3 of 0.2 N H2SO4 is mixed with 50 cm3 of 1 N KOH, the heat liberated is