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Q.

When 800 mL of 0.5 M nitric acid is heated in a beaker, its volume is reduced to half and 11.5 g of nitric acid is evaporated. The molarity of the remaining nitric acid solution is x×10-2M. (Nearest Integer)
(Molar mass of nitric acid is 63 g mol-1)

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answer is 54.

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Detailed Solution

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800mL of 0.5MHNO3 contains 0.4mol of HNO3
0.4 mol HNO3 contains 0.4×63=25.2g of HNO3
As 11.5 g of HNO3 gets evaporated and volume reduced half,
25.211.5=13.7g of HNO3 is present in 400mL of solution 
 New molarity is 13.763×1400×1000=54×102M
The value of 'x' is 54.

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