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Q.

When 965 amp current is passed through aqueous solution of salt X using platinum electrodes for 10 sec, the volume of gases liberated at the respective electrodes is in 1:1 ratio. Then X is

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a

MgSO4

b

AgCl

c

MgCl2

d

KNO3

answer is C.

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Detailed Solution

Total charge passed = i x t = 965 X 10 =9650 coulombs. 

When same quantity of charge is passed , the products formed ast anode and cathode are ; 

MgSO4 electrolysed ;at cathode H2 and at anode O2 are formed in 2:1 ratio. 

AgNO3 electrolysed ; at cathode Ag and at anode O2 are formed in 4:1 ratio. 

MgCl2 electrolysed ; at cathode  H2 and at anode Cl2 are formed in 1:1 ratio. 

KNO3 electrolysed ; At cathode H2 and at anode O2 are formed in 2:1 ratio. 

 

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When 965 amp current is passed through aqueous solution of salt X using platinum electrodes for 10 sec, the volume of gases liberated at the respective electrodes is in 1:1 ratio. Then X is