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Q.

when a certain conductance cell was filled with KCI solution (conductivity = 0.03Ω1cm1) was it had a resistance of 100Ω at 300 K temperature when filled with 0.01 MK2SO4, it has a resistance of 300Ω. Calculate molar conductivity of K2SO4 solution in terms of Ω1m2mol1.

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a

10-1

b

10-5

c

105

d

10-3

answer is C.

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Detailed Solution

KKCl=G×G0.03=1100×GG=3KK2SO4=1300×3=102Ω1cm1=1Ω1m1ΛM=1×1030.01=0.1Ω1m2mol1

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when a certain conductance cell was filled with KCI solution (conductivity = 0.03Ω−1cm−1) was it had a resistance of 100Ω at 300 K temperature when filled with 0.01 MK2SO4, it has a resistance of 300Ω. Calculate molar conductivity of K2SO4 solution in terms of Ω−1m2mol−1.