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Q.

When a co-ordination compound ${CrCl}_{3} .6 H_{2} O$ is mixed with ${AgNO}_{3}$ , 2 moles of AgCl are precipitated per mole of the compound. Write
(i) Structural formula of the complex.
(ii) IUPAC name of the complex
(iii)Write the chemical reactions involved.

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Detailed Solution

(a) $[Cr (H_{2} O_{5}) {Cl}_{1}] {Cl}_{2} . H_{2} O$
(b) Pentaaquachloridochromium (III) chloride monohydrate
(c) The complex formed on mixing a coordination compound ${CrCl}_{3} .6 H_{2} O$ with ${AgNO}_{3}$ is as follows
${CrCl}_{3} . 6 H_{2} O + {AgNO}_{3} \to [Cr (H_{2} O_{5}) Cl] {Cl}_{2} . H_{2} O$

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When a co-ordination compound CrCl3.6H2O is mixed with AgNO3, 2 moles of AgCl are precipitated per mole of the compound. Write (i) Structural formula of the complex. (ii) IUPAC name of the complex(iii)Write the chemical reactions involved.