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When a mixture containing $P C l_{3}$ and $P C l_{5}$ is heated with excess $C_{2} H_{5} O H$ total of 4 moles of $C_{2} H_{5} C l$ is formed. Mole ratio of $P C l_{3}$ and $P C l_{5}$ in the mixture is

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$3 : 1$

$1 : 3$

$1 : 1$

$2 : 1$

answer is C.

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Detailed Solution

$3 C_{_{2}} H_{5} O H + P C l_{3} \overset{Δ}{\to} 3 C_{2} H_{5} - C l + H_{3} P O_{3}$

C₂H₅OH + PCl₅−→ C₂H₅−Cl + H−Cl + POCl₃

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