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When a mixture containing PCl₃and PCl₅is heated with ethyl alcohol, a total of 4 moles of ethyl chloride is formed. Mole ratio of PCl₃and PCl₅in the mixture is

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3 : 1

1 : 1

1 : 3

2 : 1

answer is B.

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Detailed Solution

3C₂H₅OH+PCl₃→3C₂H₅Cl+H₃PO₃

C₂H₅OH+PCl₅→C₂H₅Cl+POCl₃+HCl

These are the reaction mole ratio of PCl₃and PCl₅of 1: 1

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