Q.

When a salt is heated with dilute H2SO4 and KMnO4 solution, the pink colour of KMnO4discharged, the salt is:

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a

a bicarbonate

b

a carbonate

c

a nitrate

d

a sulphite

answer is A.

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Detailed Solution

KMnO4 is an oxidizer, hence salt must have an anion that can oxidise to a higher oxidation state. Salt must therefore contain sulphide SO32which, when oxidised with KMnO4 offer SO42 (sulphate and KMnO4) himself is lowered to MnO2 e.g., the pink hue of KMnO4 discharge.

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