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Q.

When a solution containing w g of urea in 1 kg of water is cooled to 0.372oC, 200 g of ice is separated. If Kf for water is 1.86 K kg mol-1, w is 

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a

12.0 g

b

4.8 g

c

6.0 g

d

9.6 g

answer is C.

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Detailed Solution

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Mass of water present in the solution at the freezing pt. 

          =1000200=800g

ΔTf=0.372=1000×kfw60×800=1000×1.86×w60×800w=9.6g

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