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Q.

When an electric current is passed through acidified water, 112ml of hydrogen gas at N.T.P was collected at the cathode in 965 seconds. The current passed in ampere is 

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a

1.0

b

0.5

c

0.1

d

2.0

answer is A.

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Detailed Solution

2H(aq)+ + 2e-  H2(g)
At NTP, 22.4 L (or 22400 mL) of H2 = 1 mole of H2 
112 ml of H2= 11222400× 1
= 0.005 moles   of  H2
moles    of   H2=i(A) t(S)96500c /mole× mole  ratio
0.005  ml  = i(A) ×  965(S)96500 c / mole× 1  mole  H22
i = 1A

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