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Q.

When aqua regia dissolves HgS, the function of the HCl in the mixture is to

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a

oxidize the sulphur

b

complex the mercury

c

complex the sulphur

d

oxidize the mercury

answer is D.

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Detailed Solution

Aqua regia functions as both an oxidising and a complexing agent while dissolving HgS. The NO3- ions oxidise the S2- ions to free sulphur and the Cl ions to soluble complex-ions, HgCl42-, in the presence of hydronium ions.

3HgSS+2NO3-+8H3O++12Cl-3HgCl42-+2NO+3 S+12H2O

Thus, When aqua regia dissolves HgS, the function of the HCl in the mixture is to complex the mercury.

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