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Q.

When aqueous solution of sodium ethanoate is electrolysed, the volume of gases obtained at anode pressure of 1.0 bar and 298 K temperature when 2.0 Faraday of electricity is passed is:

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a

67.2 litres

b

68.1 litres

c

73.2 litres

d

7 4.1 litres

answer is D.

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Detailed Solution

For 2e- or 2F,3 mol of gases 12 mol of CO2, + 1 mol of CH3-CH3 (g)l are produced.
At 1.0 bar pressure and 298 K, volume of 1 mol of gas :24.7 litres.
 Volume of gases at anode = 24.7 x 3 : 74.1 litres

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