Q.

When borax is heated with CoO on a platinum loop, blue coloured bead formed islargely due to : 

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a

B2O3

b

CoBO22

c

CoB4O7

d

CoB4O5(OH)4

answer is B.

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Detailed Solution

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Borax Na2B4O710H2O on heating gets fused and loses water of crystallisation. It swells up into a fluffy white porousmass which then melts into a colourless liquid and forms a clear transparent glass bead consisting of boric anhydride andsodium metaborate. 
Na2B4O7.10H2OΔNa2B4O7Δ2NaBO2+ BBr2O3
Boric anhydride is non-volatile. When it is reacted with a coloured metallic salt, a characteristic coloured bead of metalmetaborate is formed. Thus, when reacted to cobalt oxide, forms blue coloured CoBO22 bead.
B2O3+CoO CoBO22
           Cobalt metaborate (blue bead)

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