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Q.

When conc. H2SO4 was treated with K4[Fe(CN)6]CO gas was evolved. By mistake, somebody used dilute H2SO4 instead of conc. H2SO4,then the gas evolved was

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a

N2

b

HCN

c

CO2

d

CO 

answer is B.

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Detailed Solution

K4[Fe(CN)6] + 6H2SO4conc. + 6H2O 2K2SO4 + FeSO4 + 3(NH4)2SO4 + 6CO

K4[Fe(CN)6] + 3H2SO4dil.2K2SO4 + FeSO4 + 6HCN

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